The purpose of the present study was to investigate different biomechanical variables of backstroke technique in swimmers specialized in different distance events, in order to investigate the capacity to modify the timing of the arm stroke when changing the swimming velocity from sub-maximal to maximal. Two 25-m backstroke trials respectively at 70% of maximum velocity (V70) and at 100% of maximum velocity (Vmax) were performed by 9 200-m distance swimmers and 9 50-m distance swimmers. Swimming velocity, stroke length, stroke rate, duration of different phases of the arm stroke and selected kinematic variables were assessed in both cases. In the 50-m distance swimmers, the duration of the propulsive phase at Vmax, expressed as a percentage of the duration of the total underwater arm stroke, increased significantly (p = 0.001) with increasing swimming velocity. Specifically, both the pull and push phases were fundamental in the increase of duration of the propulsive phase. When compared to 200-m specialists, 50-m distance swimmers seem to be more able to modify their arm stroke phases duration when increasing the swimming velocity in backstroke.